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吸热型碳氢燃料的核磁共振和色谱/质谱分析及热力学性质
测定两种吸热型碳氢燃料的1 H 和13 C NMR谱,从NMR等实验数据计算得到平均分子结构参数.以基团贡献法为桥梁,总结定量结构-性能关系,从NMR结构信息预测了燃料的蒸发焓和燃烧焓,与热力学实验结果吻合良好.用GC/MS分析燃料的化学组成,检出主要由脂肪烃、芳烃和环烷烃3类构成的60余种烃类化合物,为吸热型碳氢燃料的结构和特性表征以及燃料的开发提供重要信息.
作者单位：
浙江大学化学系,杭州,310027
ISTICSCIPKU
年，卷(期)：
机标分类号：
在线出版日期：
基金项目：
国家高技术研究发展计划(863计划)，浙江省分析测试基金
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万方数据知识服务平台--国家科技支撑计划资助项目（编号：2006BAH03B01）(C)北京万方数据股份有限公司
万方数据电子出版社第十二章 色谱分析法
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第十二章 色谱法原理
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